Aromatic 03
Aromatic 03 : An aromatic molecule or compound is one that has special stability and properties due to a closed loop of electrons. Not all molecules with ring (loop) structures are aromatic. A general scientific definition can be found below. Aromatic molecules are sometimes referred to simply as aromatics. Molecules that are not aromatic are termed aliphatic. If a molecule contains an aromatic sub-unit, this is often called an aryl group. A prototypical aromatic compound is benzene, so a layperson might prefer to think of an aromatic compound as something that has a ring structure like that of benzene, C6H6. Shown here are 4 equivalent ways of representing the structural formula of benzene where C = a carbon atom, H = a hydrogen atom and a line is a chemical bond. Additional Info: An introductory organic chemistry definition of an aromatic compound is one that has a planar ring with 4n + 2 pi-electrons where n is a non-negative integer (H?ckel's Rule). For those with limited chemistry experience, in the drawings of benzene above there are six pi-electrons. If you look at the first or third drawing, the double lines (bonds) between carbon atoms each have 2 pi-electrons. There are 3 double bonds in these drawings, and therefore six pi-electrons. Systems with six pi-electrons in a planar ring are aromatic according to H?ckel's Rule where n = 1, i.e. 4(1) + 2 = 6. Aspiring chemists will note that our current discussion is omitting a feature of aromatic molecules called resonance that explains their chemical properties. For detailed information about the special chemical properties and chemistry of aromatic molecules, See: The Further Reading links below. The term "aromatic" was used by chemists to describe certain chemicals with peculiar odors long before anyone understood what atoms were or how they might be connected to form molecules. Many aromatic molecules such as benzene and those shown below have distinctive odors (aromas), but not all aromatic molecules have an odor. Aromatic molecules containing several fused (joined) rings are called polycylic aromatics or sometimes simply "polycyclics" for short. Those polycyclic aromatics made up only of carbon and hydrogen are called polycyclic aromatic hydrocarbons or PAH's. Many PAH's are extremely potent carcinogens ormutagens. For example, the molecule shown on the right, benzo[a]pyrene is an exceedingly potent carcinogen found commonly in coal tar and soot, including tobacco smoke and diesel exhaust! Side note: PAH's don't always appear to obey H?ckel's Rule, but individual rings or groups of rings in the molecule do. MSDS Relevance: A compound that has an odor is not necessarily aromatic. Likewise, not all aromatic molecules have an odor. When the term aromatic is used in an MSDS it is referring to the chemical definition of aromaticity, not the smell or odor of the compound. Treat all aromatic compounds with respect as many of them pose serious physical and health hazards such as carcinogenicity and flammability. Use proper personal protective equipment (PPE) and minimize your exposure to aromatic compounds by using proper engineering and administrative controls. See also: Aliphatic, Hydrocarbon, Organic
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